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  • Nitrogen Tetroxide - an overview | ScienceDirect Topics
    Nitrogen tetroxide is a common storable oxidizer that is hypergolic with many fuels The Occupational Safety and Health Administration lists a ceiling exposure limit of 5 parts per million with possible health hazards primarily to the lungs and irritation to the eyes, nose, and throat
  • Dinitrogen Tetraoxide - an overview | ScienceDirect Topics
    Dinitrogen tetraoxide, also known as nitrogen tetroxide, is a chemical compound with the molecular formula N2O4 AI generated definition based on: Encyclopedia of Toxicology (Third Edition) , 2014 About this page
  • Osmium Tetroxide - an overview | ScienceDirect Topics
    Osmium tetroxide-2,2′-bipyridine was the first reagent reported to probe DNA structure in vivo, providing evidence for the existence of Z-DNA in the cell 129 Osmium(VIII) tetroxide (OsO 4) in the presence of pyridine bipyridine adds to the 5,6 double bond of thymine to form an osmate ester, which can then be cleaved with piperidine to allow
  • The chemical nature of osmium tetroxide fixation and staining of . . .
    Reaction of osmium tetroxide with glutaraldehyde Equal volumes of 50 ~ aqueous glutaraldehyde and 4 ~o aqueous osmium tetroxide solutions were mixed (tool ratio 30 : 1) and held overnight at 4 °C 5 #1 of the resulting black suspension was applied to a sample plate, and the ESCA spectrum was obtained (60; 1080)
  • Osmium Tetraoxide - an overview | ScienceDirect Topics
    Osmium tetroxide (OsO 4) is both a dye and a fixative While it is primarily used as a fixative agent in electron microscopy (high electron scattering rate without the need for coating the membrane with a layer of metal, which can obscure details of the cell membrane), it is well suited to reveal the details of myelin in nerves because it binds to lipids strongly
  • Osmium Tetroxide - an overview | ScienceDirect Topics
    Osmium Tetroxide Method Osmium tetroxide is the chemical compound with the formula OsO 4 The compound is noteworthy for its many uses, despite the rarity of osmium Pure OsO 4 is colorless and volatile; it has a characteristic acrid chlorine-like odor and is soluble in a wide range of organic solvents It is also moderately soluble in water
  • Toxic tips: Osmium tetroxide - ScienceDirect
    In the past, osmium tetroxide was used as a fingerprinting agent, but this use was discontinued because it caused cases of contact dermatitis 6 Now, in the laboratory, osmium tetroxide is mainly used as a fixative or as a histological stain for fat in electron microscopy 1, 7 It acts as a catalyst for chlorate, peroxide, and periodate oxidation reactions, and as an oxidizing agent in the
  • Catalytic asymmetric dihydroxylation of olefins using polysulfone-based . . .
    Osmium catalyzed dihydroxylation of olefins is one of the most efficient methods for the preparation of vicinal diols 1 In particular, the asymmetric dihydroxylation of olefins using catalytic amounts of osmium tetroxide in the presence of chiral ligands allows access to a wide variety of enantiomerically pure vicinal diols 2 In 1992, Sharpless et al reported a catalytic system based on bis
  • The Oxidation of Organic Compounds by Ruthenium Tetroxide
    Oxidation by Ruthenium Tetroxide T A B L E II THE OXIDATION OF ALKENES AND DIENES BY RUTHENIUM TETROXIDE 191 Reactant 2-Butene 1-Hexene 3-Heptene Product Acetaldehyde Valeric acid Butanoic acid, propanoic acid Heptaldehyde 3-Heptanone N o oxidation product Conditions B A A, Various A C A A A A A A A A A A A C A A A A A A C -- 0 Yield (%) 60 51





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